I was thinking of MF & how its drop is 80 degrees, then couldn't think of a steeper one. Forget X, HS:XLC, Oblivion (it's specifically designed to have a 'vertical drop,' just look at it's trains,) Xcelerator & others.
I wonder if we will see a 90 degree drop on a traditional coaster, perhaps the Heide Park Tera will have one?